The following characters are available to be played as in multiplayer. For an overview of characters that appeared in singleplayer, see the info under the pictures or go here.

TEAM MI6

MI6 STEALTH	MI6 TUX	MI6 SUIT	ALURA
Also in singleplayer	Also in singleplayer	Also in singleplayer	Also in singleplayer
DOMINIQUE	ZOE	Q	CHRISTMAS JONES
Also in singleplayer	Also in singleplayer	Also in singleplayer	Not in singleplayer
PUSSY GALORE	WAI LIN
Not in singleplayer	Not in singleplayer

TEAM PHOENIX

CASTLE GUARD	COMMANDO	DRAKE	KIKO
Also in singleplayer	Also in singleplayer	Also in singleplayer	Also in singleplayer
ROOK	SNOW GUARD	YAKUZA	MAYDAY
Also in singleplayer	Also in singleplayer	Also in singleplayer	Not in singleplayer
XENIA	JAWS	ODDJOB	ELEKTRA
Not in singleplayer	Not in singleplayer	Not in singleplayer	Not in singleplayer
GOLDFINGER	BARON SAMEDI	RENARD	SCARAMANGA
Not in singleplayer	Not in singleplayer	Not in singleplayer	Not in singleplayer

However Nic Nak has his own picture in the game data, he cannot be played as and also doesn’t show elsewhere in the game.